SYNTHESIS AND CHARACTERIZATION OF BIOPOLYMERS FROM SESAME OIL WITH VINYL ACETATE AND N-VINYL-2- PYRROLIDONE CO-MONOMERS

  • Irin Sheela. C Lord Jegannath College of Engineering and Technology, Nagercoil, Tamilnadu, India
  • Begila David. S Scott Christian College, Nagercoil, Tamilnadu, India
Keywords: Biopolymer, Biodegradation, Free radical polymerization

Abstract

In this study biodegradable polymers were synthesised by the polymerization of sesame oil monoglyceride cyclohexane dicarboxylate with comonomers like vinyl acetate(VA) and N-vinyl-2-pyrrolidone (VP). Glycerolysis of sesame oil was first carried out at 220 - 230°C to prepare monoglyceride of sesame oil(SOMG). Then the resin was prepared by the reaction of the monoglyceride with cyclohexane dicarboxylic anhydride at 80°C for 2 hours.

References

H. Uyama, T. Kuwabara, T. Tsujimoto, S. Kobayashi, Biomacromolecules 2003, 4, 211.

B. Hazer, ‘‘Chemical Modification of Synthetic and Biosynthetic Polyesters’’, in: Biopolymers, Vol. 10, A. Steinbu¨chel, Ed., Wiley-VCH, Weinheim 2003, Chapter 6, p. 181–208.

a. R. W. Lenz, Adv. Polym. Sci. 1993, 1, 107; b. Y. Doi, ‘‘Microbial Polyesters’’, Wiley, New York 1993; c. F. Li, D.W. Marks, R. C. Larock, J. U. Otaigbe, Polymer 2000, 41, 7925; d. J. Yu, J. Gao, T. Lin, J. Appl. Polym. Sci. 1996, 62, 1491.

Williams, C.K., and Hillmeyer, M.A., 2008. Polymers from renewable resources: A perspective for reviews. Polym. Rev. 48: 1–10.

Baumann H, Bühler M, Fochem H, Hirsinger F, Zoebelein H, Falbe J. Natürliche Fette und Öle – nachwachsende Rohstoffe für die chemische Industrie. Angew Chem 1988;100:41–62. [6] Gunstone F. Fatty acid & lipid chemistry. New York:BlackieAcademic & Professional; 1996. p. 1–252.

. S. Panigrahi, X. Li, S. Panigrahi, R. L. Kushwaha. Development of Flax oil-based Biopolymer for Biocomposites

M.R.Van,DeMark and K. Sandefur, in Industrial Uses of Vegetable Oil, ed. S. Z. Erhan, AOCS Press, Peoria, IL, 2005, ch. 8, pp. 143–162.

A. Demirbas, Energy Sources, Part A: Recovery, Util. Environ. Eff., 2010, 32, 628–636.

Park, S.J., Jin, F.L., and Lee, J.R., 2004. Syntheses and thermal properties of epoxidised vegetable oil. Macromol. Rapid Comm. 25: 724-727.

. Güner, F. S.; Yağcı, Y.; Erciyes, A. T. Prog Polym Sci 2006, 31, 633-670.

D. D. Andjelkovic, M. Valverde, P. Henna, F. K. Li and R. C. Larock, Polymer, 2005, 46, 9674– 9685.

Gultekin M., Beker U., Güner F. S., Erciyes A. ., Yagci Y.: Styrenation of castor oil and linseed oil by macromer method. Macromolecular Materials and Engineering, 283, 15–20 (2000).

Li F., Larock R. C.: Synthesis, structure and properties of new tung oil-styrene-divinylbenzene copolymers prepared by thermal polymerization. Biomacromolecules, 4, 1018–1025 (2003).

Kundu P. P., Larock R. C.: Novel conjugated linseed oil-styrene-divinylbenzene copolymers prepared by thermal polymerization. 1. Effect of monomer concentration on the structure and properties. Biomacromolecules, 6, 797–806 (2005).

Li F., Hanson M. V., Larock R. C.: Soybean oil divinyl benzene thermosetting polymers: Synthesis, structure, properties and their relationships. Polymer, 42, 1567–1579 (2001).

Li F., Larock R. C.: New soybean oil-styrene-divinyl benzene thermosetting copolymers. I. Synthesis and characterization. Journal of Applied Polymer Science, 80, 658–670 (2001).

Li F., Larock R. C.: Thermosetting polymers from cationic copolymerization of tung oil: Synthesis and characterization. Journal of Applied Polymer Science, 78, 1044–1056 (2000).

Li F., Hasjim J., Larock R. C.: Synthesis, structure and thermophysical and mechanical properties of new polymers prepared by the cationic copolymerization of corn, styrene and divinylbenzene. Journal of Applied Polymer Science, 90, 1830–1838 (2003).

M. Elluch, S. Besbes, O. Roiseux, C. Blecker, H. Attia, Quality Characteristic of Sesame Seed and by-products, Food Chemistry 103 (2007) 641-650.

Flory P. J.: Principles of polymer chemistry. Cornell University Press, Ithaca (1953).

Nielsen L. E., Landel R. F.: Mechanical properties of polymers and composites. Marcel Dekker, New York (1994).

Gandini, A., 2008. Polymers from renewable resources: a challenge for the future of macromolecular materials. Macromolecules 41: 9491–9504. [24]. M. Karunanithi, R. Nanthini, A. Ravi & V. JaiSankar. Synthesis and characterization of biodegradable aliphatic polyester. Asian Journal of Chemistry, Vol.22. No. 10 (2010) 7699 – 7705.

Hamurcu E., Baysal B. M.: Interpenetrating polymer networks of poly (dimethylsiloxane). Preparation and characterization. Polymer, 34, 5163–5167 (1993).

. Annelise E. Gerbase, Cesar L. Petzhold, and Ana Paula O. Costa, Dynamic Mechanical and Thermal behavior of epoxy resins based on soybean oil, JAOCS, Vol.79, no.B(2002).
Published
2015-06-30
Section
Case Report